Other beryllium products: Beryllium Nitride (Be3N2), Beryllium Foil (Be Foil), Beryllium Sheet (Be Sheet), Beryllia It does not represent a new labelling, classification or hazard statement, neither reflect other factors that affect the susceptibility of the effects described, such as duration of exposure or substance concentration (e.g. beryllium;sulfate . It is possible that a harmonisation is introduced through an amendment to the CLP Regulation. Inhaled water-soluble beryllium salts are excreted mainly by the kidneys, with a half-life of 2-8 weeks (Zorn et al., 1988). Note that this list is not exhaustive. The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. (1) Pure beryllium is insoluble in water; however, some of its compounds are soluble in water. Berylliumsulfid [German] [ACD/IUPAC Name] Sulfure de béryllium [French] [ACD/IUPAC Name] 13598-22-6 [RN] Predicted - ACD/Labs; Predicted - ChemAxon; Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module. Molecular Weight 177.14 . Picture of reaction: Сoding to search: BeSO4 + 2 NaOH = BeOH2 + Na2SO4. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. BaSO4. Employers are obligated to prevent the exposure of these workers to any agents that may have adverse health effects on either mother or child. Solubility of the sulphates. Beryllium is soluble in hot nitric acid, dilute hydrochloric and sulfuric acids, and sodium hydroxide. This simple trend is true provided hydrated beryllium sulfate is considered, but not anhydrous beryllium sulfate. Beryllium sulfate normally encountered as the tetrahydrate, [Be(H 2 O) 4]SO 4 is a white crystalline solid. The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. EU. Product Identification Synonyms: Beryllium sulphate tetrahydrate; Sulfuric acid, beryllium salt (1:1), tetrahydrate CAS No. This produces toxic fumes of sulfur oxides (see ICSC 0074) and beryllium oxide (see ICSC 1325). 7.1.3 Dermal Beryllium Carciiiogenesis II. the electronic edition of the Official Journal of the European Union. Beryllium sulfate, in the anhydrous form, absorbs water to become the tetrahydrate immediately upon contact. They react as bases to neutralize acids. Substances listed in the EINECS, ELINCS, or NLP inventories. Pure beryllium metal is used to make aircraft disc brakes, nuclear weapons and reactors, aircraft-satellite-space vehicle structures a… InfoCards are generated automatically based on the data available at the time of generation. Help. ECHA organises consultations to get feedback from all interested parties and to gather the widest possible range of scientific information for the regulatory processes. Some substance identifiers may have been claimed confidential, or may not have been provided, and therefore not be displayed. Note that for readability purposes, only the pictograms, signal words and hazard statements referred in more than 5% of the notifications under CLP are displayed. Beryllium sulfate BeSO4 37 37.6 39.1 41.4 45.8 53.1 67.2 82.8 Bismuth arsenate BiAsO4 0.0007298 Bismuth hydroxide Bi(OH)3 2.868E-07 Bismuth iodide BiI3 0.0007761 Bismuth phosphate BiPO4 1.096E-10 Bismuth sulfide Bi2S3 1.561E-20 Boric acid H3BO3 2.52 4.72 8.08 10.27 12.97 19.10 27.53 Solubility table - Wikipedia, the free encyclopedia Page 3 of 18 The synergetic effect in beryllium sulfate tetrahydrate - an experimental electron-density study. For full table with Density, Liquid Denity at Melting Point and Water Solubility-rotate the screen! 6H2O which contains an octahedral Mg(OH2)62+ unit. The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. Other . Beryllium is poorly absorbed from the gastrointestinal tract, probably because as soluble beryllium sulfate passes into the intestine, which has a higher pH, the beryllium is precipitated as the insoluble phosphate and thus is no longer available for absorption (Reeves, 1965). For price and availability of parts call: 360-425-1119 email: parts@averysaircooled.com GHS Hazard and Precautionary Statements Substances, Mixtures, Related Processes: Annex I & Article 2, Directive 2004/37/EC (CMD), as amended by Directive 2019/130/EU, 31 January 2019, EU. This list contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class and category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive 2008/98/EC. This information is only displayed if the substance is well-defined, its identity is not claimed confidential and there is sufficient information available in ECHA’s databases for ECHA’s algorithms to generate a molecular structure. Beryllium sulfate may be prepared by treating an aqueous solution of any beryllium salt with sulfuric acid, followed by evaporation of the solution and crystallization. Our channel. This information has not been reviewed or verified by ECHA, and may change without prior notice. stream The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. (1) Pure beryllium is insoluble in water; however, some of its compounds are soluble in water. Substances according to Hazardous Waste Properties: Annex III, Directive 2008/98/EC, 22 November 2008, amended by Directive 2018/851/EU, 14 June 2018, Registration, Evaluation, Authorisation and Restriction of Chemicals, Chemical Agents Directive and Carcinogens or Mutagens Directive, Protection of Pregnant and Breastfeeding Workers Directive, Safety and/or Health Signs at Work Directive, EC Inventory, C&L Inventory, Pre-Registration process, Other, Substances of very high concern identification, Recommendation for the Authorisation List, Getting started with EU chemicals legislation, Classification of substances and mixtures, Harmonised classification and labelling (CLH). Non-Exhaustive List of Banned Substances, Directive 94/33/EC on Young People at Work, 20 August 1994, as amended by Dir 2014/27/EU, March 5, 2014 (Based on Table 3 of Annex VI to CLP, inter alia), EU. In that case, the ATP (Adaptation to Technical Progress) number is displayed. Sigma-Aldrich offers a number of Beryllium sulfate tetrahydrate products. The CLP Regulation makes sure that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union. The source of the information is mentioned in the introductory sentence of the hazard statements. Decomposes above 550°C . For price and availability of parts call: 360-425-1119 email: parts@averysaircooled.com Here you can find all of the regulations and regulatory lists in which this substance appears, according to the data available to ECHA. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. Obtaining Beryllium sulfate: Substances predicted as likely to meet criteria for category 1A or 1B carcinogenicity, mutagenicity, or reproductive toxicity. Other beryllium products: Beryllium Nitride (Be3N2), Beryllium Foil (Be Foil), Beryllium Sheet (Be Sheet), Beryllia While reprocessing is ongoing please note that substances whose registration dossiers are not yet processed can incorrectly state in the Infocard that they are not registered under REACH. This list contains a non-exhaustive inventory of substances based on Art. They react as bases to neutralize acids. Beryllium has a strong resistant layer of oxide on its surface which lowers its reactivity at ordinary temperatures. EC Number 236-842-2. Beryllium sulfate BeSO4 37 37.6 39.1 41.4 45.8 53.1 67.2 82.8 Bismuth arsenate BiAsO4 0.0007298 Bismuth hydroxide Bi(OH)3 2.868E-07 Bismuth iodide BiI3 0.0007761 Bismuth phosphate BiPO4 1.096E-10 Bismuth sulfide Bi2S3 1.561E-20 Boric acid H3BO3 2.52 4.72 8.08 10.27 12.97 19.10 27.53 Solubility table - Wikipedia, the free encyclopedia Page 3 of 18 The hydrated product may be converted to anhydrous salt by heating at 400 °C. The sulphates become less soluble as you go down the Group. Salts, basic, such as BERYLLIUM SULFATE TETRAHYDRATE are generally soluble in water. We also produce Beryllium Sulfate Powder. 1. disodium tetraborate EC no. When going down the group is A. solubility of group 2 … Properties of Beryllium sulfate: White, melts without decomposition, upon further heating decomposes. If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. at ANSTO, Lucas Heights). The EC Inventory is a combination of three independent European lists of substances from the previous EU chemicals regulatory frameworks (EINECS, ELINCS and the NLP-list). When information is available in all sources, the first two are displayed as a priority. While the harmonised list covers many hazardous substances, others not listed may also meet the classification criteria in accordance with the CLP Regulation. InfoCards are updated when new information is available. Most of the beryllium ore mined is processed into beryllium oxide which is then reduced to beryllium metal or converted to various beryllium compounds. in case of consumer and professional uses). barium sulfate = insoluble. 1994, B50, (3), 316-326. ... takes place at a temperature of 220-400°C. However, substance notifications in the InfoCard are aggregated independently of the impurities and additives. Substances may have impurities and additives that lead to different classifications. Water solubility of beryllium and its salts varies, with beryllium chloride, fluoride, nitrate, phosphate, and sulfate all being soluble in water. Stanford Advanced Materials (SAM) provides good quality beryllium sulfide (BeS) powder with competitive price. 4H 2 O . The EU Ecolabel may not be awarded to substances or mixtures classified as such. No predicted properties have been calculated for this compound. Beryllium sulfate may be prepared by treating an aqueous solution of any beryllium salt with sulfuric acid, followed by evaporation of the solution and crystallization. The quality and correctness of the information submitted to ECHA remains the responsibility of the data submitter. About Beryllium Sulfate Tetrahydrate Beryllium Sulfate is a moderately water and acid soluble Beryllium source for uses compatible with sulfates. Beryllium carbonate, sulfate (tetrahydrate), and hydroxide are formed during the processing of beryllium containing ores into beryllium metal. If no EU harmonised classification and labelling exists and the substance was not registered under REACH, information derived from classification and labelling (C&L) notifications to ECHA under CLP Regulation is displayed under this section. Sinks in water and dissolves. Beryllium Sulfide is a moderately water and acid soluble Beryllium source for uses compatible with sulfates. beryllium sulphide. 1994, B50, (3), 316-326. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. The table below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure.Units of solubility are given in grams per 100 millilitres of water (g/100 mL), unless shown otherwise. Please upgrade your Internet Explorer to a newer version. Acta Cryst. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Include hydrated beryllium sulphate is slightly soluble and barium sulphate is insoluble simple trend is true hydrated. Salts, basic, such as BERYLLIUM SULFATE TETRAHYDRATE are generally soluble in water. Substances indicated, in 2009, as being intended to be registered by at least one company in the EEA. : 13510-49-1 (Anhydrous); 7787-56-6 (Tetrahydrate) Molecular Weight: 177.15 Chemical Formula: BeSO4 . Decomposes above 550°C . Employers are obligated to minimize worker exposure to these agents as far as possible, and must arrange for medical surveillance of workers exposed to these substances. Beryllium is also present in a variety of compounds such as beryllium fluoride, beryllium chloride, beryllium sulfate, beryllium oxide, and beryllium phosphate. REACH registration dossiers have greater data requirements (such as supporting studies) than do notifications under CLP. 13510-49-1 . It covers their hazardous properties, classification and labelling, and information on how to use them safely. Insoluble in alcohol. Group parents . Ammonium & Alkali ONLY. beryllium(2+) sulfate . Beryllium oxide was negative in the Ames assay and Bacillus subtilis rec assay (Kuroda et al., 1991). 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. This substance has been found in the following regulatory activities (directly, or inheriting the regulatory context of a parent substance): This list contains a non-exhaustive inventory based on the list of substances with harmonised classification and labelling (i.e., Table 3 of Annex VI to the CLP Regulation 1272/2008/EC). This reaction takes place at a temperature of 220-400°C. The POPs Regulation bans or severely restricts the production and use of persistent organic pollutants in the European Union. 7.1.3 Dermal (1) … NONCARCINOGENIC HEALTH EFFECTS 1. 215–540–4, is covered by three harmonisations: 005–011–00–4; 005–011–01–1 and 005–011–02–9), CLH information cannot be displayed in the InfoCard as the difference between the CLH classifications requires manual interpretation or verification. The Prior Informed Consent Regulation administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries. BERYLLIUM SULFATE BeSO4. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Harmonised classification and labelling is a legally binding classification and labelling for a substance, agreed at European Community level. The substances are listed in alphabetical order. The type of uses and classifications may vary between different submissions to ECHA and for a full understanding it is recommended to consult the source data. Beryllium Sulfate is a white colored, crystalline, inorganic compound that emits toxic fumes of beryllium oxides and sulfur oxides upon heating. T The tetrahydrate contains a tetrahedral Be (OH 2) 42+ unit and sulfate anions. The InfoCard summarises the non-confidential data of a substance held in the databases of the European Chemicals Agency (ECHA). SOLUBILITY OF THE HYDROXIDES, SULPHATES AND CARBONATES OF THE GROUP 2 ELEMENTS IN WATER This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, … Boiling point - the temperature at which a liquid turns into a gas; Melting point - the temperature at which a solid turns into a liquid; See Standard state and enthalpy of formation, Gibbs free energy of formation, entropy and heat capacity for thermodynamic data for the same compounds. Inhalation exposure to its dust and fumes irritates the nose, throat and lungs and can cause pneumonitis. BERYLLIUM SULFATE BeSO4. The list is a non-exhaustive inventory of such substances based on: 1) agents of risk groups 3 and 4 under Directive 2000/54/EC; 2) Table 3 of Annex VI to the CLP Regulation; 3) and Annex I of Directive 2004/37/EC. A prioritisation hierarchy means that data is taken from harmonised C&L data and regulatory lists first, then REACH registrations and finally from CLP notifications. According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance is fatal if inhaled, is toxic if swallowed, may cause cancer by inhalation, causes damage to organs through prolonged or repeated exposure, is toxic to aquatic life with long lasting effects, causes serious eye irritation, causes skin irritation, may cause an allergic skin reaction and may cause respiratory irritation. 4H 2O 177.133.91⋅10 6 mg/l** Beryllium fluoride 7787-49-7 BeF The date of the last update corresponds to the publication date of the InfoCard and not necessarily to the date in which the update occurred in the source data. Include hydrated beryllium sulphate is slightly soluble and barium sulphate is insoluble simple trend is true hydrated. PubChem Substance ID 24852118. The correct total tonnage band can be found in the factsheet(s) for the substance. The thermal decomposition of tetrahydrate beryllium sulfate to produce beryllium sulfate and water. While the harmonised list covers many hazardous substances, others not listed may also meet classification criteria in accordance with the CLP Regulation. The solubility of the tetrahydrate form in cold water is 42.5 grams/100 mL of water at 25°C. This list contains biological and chemical agents, in accordance with Art. NACRES NA.22 The molecular structure is based on structures generated from information available in ECHA’s databases. Properties of concern are calculated at four "levels" of certainty: The following properties of concern are calculated: The substance properties displayed in this section are derived from Harmonised classification and labelling (CLH) data, entries in the Candidate list of substances of very high concern for authorisation, the PBT assessment list, the ED assessment list, REACH registered dossier data and from notifications made under CLP. Details of the improvements can be found at. However, the oxide layer breaks up above 750°C and exposes the beryllium metal surface below it, ... Less precipitate is formed down the group with increasing solubility. Obtaining Beryllium sulfate: The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. Thermodynamic properties of substances The solubility of the substances Periodic table of elements. The tetrahydrate contains a … The Be-O distance is 156 pm and the S-O distance is 150 pm.[7]. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. The Support section provides tools and practical guidance to companies which have responsibilities under the EU chemicals legislation. Pulmonary alveolar macrophage cells (PAM), obtained by bronchopulmonary lavage of Beagle dogs, were exposed in vitro to beryllium oxide (BeO) particles calcined at either 500 or 1000 degrees C or to beryllium sulfate (BeSO4). Worldwide, industrial grade beryl is used as a feedstock for beryllium metal, alloys and oxide, all of which have many high-tech applications particularly in the nuclear, electronic and ceramic industries. Beryllium sulfate occurs as colorless crys-tals; it is insoluble in cold water and alcohol but decomposes in hot water. For full table with Density, Liquid Denity at Melting Point and Water Solubility-rotate the screen! hydroxide are also practically insoluble in water. Unity to U.S. 'Black Panther ' actor, model why solubility of sulphates decrease down the group romance rumors, Mass their. Beryllium sulfate react with sodium hydroxide to produce beryllium hydroxide and sodium sulfate. Beryllium Sulfide is a moderately water and acid soluble Beryllium source for uses compatible with sulfates. Hazardous Substances - Article 2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. GHS Hazard and Precautionary Statements It is readily soluble in acidified water (hydrolysis on a cation), is not dissolved in concentrated sulfuric acid. This site is not fully supported in Internet Explorer 7 (and earlier versions). If at least one company has indicated that the substance classification is affected by impurities or additives, this will be indicated by an informative sentence. A metal sulfate in which the metal is beryllium (in the +2 oxidation state) and the ratio of beryllium to sulfate is 1:1. Beryllium is resistant to corrosion; weight for weight, it is stronger than steel, and because of its low density (about 1/3 that of aluminum) it has found extensive use in the aerospace industry. It is the responsibility of the substance manufacturers and importers to consult official publications, e.g. NOTE: Although the toxicity values presented in these toxicity profiles were correct at the time they were produced, these values are subject to change. beryllium sulfate tetrahydrate,ccris 85,beryllium sulphate tetrahydrate,beryllium monosulfate tetrahydrate,unii-2tyk3lf8zn,beryllium sulfate, tetrahydrate 1:1:4,2tyk3lf8zn,sulfuric acid, beryllium salt 1:1 , tetrahydrate,beryllium sulfate tetrahydrate beryllium and beryllium compounds,dsstox_cid_4603 The overall trend, for the reactivity of Group 2 metals with water, is an increase down the group. Barium hydroxide is soluble enough to be able to produce a solution with a concentration of around 0.1 mol dm-3 at room temperature. Contents View information & documentation regarding Beryllium sulfate tetrahydrate, including CAS, MSDS & more. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Basic beryllium carbonate is a mixed salt, which can be prepared by the reaction of beryllium sulfate and ammonium carbonate, and contains both carbonate and hydroxide ions, with formula Be 2 CO 3 (OH) 2. They react as bases to neutralize acids. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. The inventory originates from Table 3 of Annex VI to the CLP. Ammonium & Alkali ONLY. A mixture of beryllium and radium sulfate was used as the neutron source in the discovery of nuclear fission. The EC Number is the numerical identifier for substances in the EC Inventory. Solvolysis/solubility: beryllium itself is virtually insoluble in water but soluble in diluted mineral acids; beryllium hydroxide, beryllium oxide: insoluble in water, beryllium nitrate: 1,033 g/l (at 20°C), beryllium sulphate 424 g/l (at 25°C) ORIGIN AND USE. Some substance identifiers may have impurities and additives that lead to different classifications workplace signage: Annexes I III! And regulatory lists in which this substance has been identified as member of the hydrogens with a half-life of weeks. Parts call: 360-425-1119 email: parts @ averysaircooled.com beryllium sulfate to produce beryllium:..., according to the CLP 1B Carcinogens and Mutagens Directive the titrations acids! 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